114772-34-8
- Product Name：4'-Methylbiphenyl-2-Carboxylic Acid Methyl Ester
- Molecular Formula：C15H14O2
- Purity：99%
- Molecular Weight：226.275
Product Details;
CasNo： 114772-34-8
Molecular Formula： C15H14O2
4'-Methylbiphenyl-2-Carboxylic Acid Methyl Ester Good Supplier In Bulk Supply High Purity 114772-34-8
- Molecular Formula:C15H14O2
- Molecular Weight:226.275
- Melting Point:60-61 °C
- Boiling Point:359.4 °C at 760 mmHg
- Flash Point:164.3 °C
- PSA：26.30000
- Density:1.083 g/cm3
- LogP:3.44860
114772-34-8 Relevant articles
Electrochemical C?O Bond Formation: Facile Access to Aromatic Lactones
Tao, Xiang-Zhang,Dai, Jian-Jun,Zhou, Jie,Xu, Jun,Xu, Hua-Jian
, p. 6932 - 6935 (2018)
An efficient and robust methodology base...
Synthesis of biaryls via cross-coupling reaction of arylboronic acids with aryl chlorides catalyzed by NiCl2/Triphenylphosphine complexes
Inada, Kaoru,Miyaura, Norio
, p. 8657 - 8660 (2000)
The cross-coupling reaction of tolylboro...
One-pot sequential reaction to 2-substituted-phenanthridinones from: N -methoxybenzamides
Liang, Dongdong,Sersen, Deanna,Yang, Chao,Deschamps, Jeffrey R.,Imler, Gregory H.,Jiang, Chao,Xue, Fengtian
, p. 4390 - 4398 (2017)
The sequential use of a hypervalent iodi...
Bis(triphenylphosphine)palladium(II)succinimide as a precatalyst for Suzuki cross-coupling - Subtle effects exerted by the succinimide ligand
Fairlamb, Ian J.S.,Kapdi, Anant R.,Lynam, Jason M.,Taylor, Richard J.K.,Whitwood, Adrian C.
, p. 5711 - 5718 (2004)
A new palladium(II) precatalyst for Suzu...
Synthesis method of 4-bromomethyl-2-methyl formate biphenyl
-
Paragraph 0025; 0029-0030; 0032; 0036-0037, (2021/07/14)
The invention discloses a synthesis meth...
Palladium-catalyzed intramolecular aromatic C-H acylation of 2-arylbenzoyl fluorides
Hayakawa, Kazuki,Ikai, Kana,Ogiwara, Yohei,Sakai, Norio,Sakurai, Yuka
, p. 1882 - 1893 (2021/08/13)
The catalytic intramolecular cyclization...
Mechanochemical-Cascaded C-N Cross-Coupling and Halogenation Using N-Bromo- And N-Chlorosuccinimide as Bifunctional Reagents
Bera, Shyamal Kanti,Mal, Prasenjit
, p. 14144 - 14159 (2021/09/13)
Exploration of alternative energy source...
N-Aroylsulfonamide-Photofragmentation (ASAP)-A Versatile Route to Biaryls
Wessig, Pablo,Krebs, Saskia
supporting information, p. 6367 - 6374 (2021/09/29)
The photochemical fragmentation of N-aro...
114772-34-8 Process route
-
- 67-56-1
methanol
-
- 7148-03-0
o-tolylbenzoic acid
-
- 114772-34-8
methyl 4'-methylbiphenyl-2-carboxylate
| Conditions | Yield |
|---|---|
|
With dmap; dicyclohexyl-carbodiimide; at 25 ℃; for 3h; Temperature; Large scale;
|
98.05% |
|
With sulfuric acid; at 60 ℃; for 12h; Large scale;
|
96.4% |
|
With sulfuric acid; for 5h; Reflux;
|
94% |
|
With acetyl chloride; Yield given. Multistep reaction; 1.) 0 deg C, 0.25 h, 2.) reflux, 4 h;
|
|
|
With sulfuric acid; for 5h; Time; Reflux;
|
13.9 g |
-
- 610-96-8
methyl chlorobenzoate
-
- 380481-66-3
5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane
-
- 114772-34-8
methyl 4'-methylbiphenyl-2-carboxylate
| Conditions | Yield |
|---|---|
|
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine; In tetrahydrofuran; at 23 ℃; for 4h; Inert atmosphere; Glovebox; Sealed tube;
|
94% |
114772-34-8 Upstream products
-
67-56-1
methanol
-
7148-03-0
o-tolylbenzoic acid
-
624-31-7
4-tolyl iodide
-
610-97-9
o-iodo-methyl-benzoic acid
114772-34-8 Downstream products
-
897446-35-4
4'-methylbiphenyl-2-carboxylic acid (2-aminophenyl)amide
-
194416-99-4
Methyl 4'-(benzotriazol-1-yl)methylbiphenyl-2-carboxylate
-
194416-97-2
Methyl 4'-(naphtho[2,3-d]imidazol-1-yl)methylbiphenyl-2-carboxylate
-
194417-01-1
Methyl 4'-(naphtho[2,3-d][1,2,3]triazol-1-yl)methyl-biphenyl-2-carboxylate
Relevant Products
-
5-(2′-Hydroxy-3′-Naphthamide)-2-BenzimidazoloneCAS：26848-40-8
-
C14 AlcoholCAS：112-72-1
-
Ethylenediaminetetraacetic AcidCAS：60-00-4
